Aluminium nitride[1]
Other names Aluminum nitride
Identifiers
CAS number	24304-00-5 Y
PubChem	90455
ChemSpider	81668 Y
ChEBI	CHEBI:50884 Y
Jmol-3D images	Image 1
SMILES [Al]#N
InChI InChI=1S/Al.N Y Key: PIGFYZPCRLYGLF-UHFFFAOYSA-N Y InChI=1/Al.N/rAlN/c1-2 Key: PIGFYZPCRLYGLF-PXKYIXAJAH
Properties
Molecular formula	AlN
Molar mass	40.9882 g/mol
Appearance	white to pale-yellow solid
Density	3.260 g/cm3
Melting point	2200 °C
Boiling point	2517 °C (decomp)
Solubility in water	decomposes
Band gap	6.2 eV (direct)
Electron mobility	~300 cm2/(V·s)
Thermal conductivity	285 W/(m·K)
Refractive index (nD)	1.9–2.2
Structure
Crystal structure	Wurtzite
Space group	C6v4-P63mc
Coordination geometry	Tetrahedral
Thermochemistry
Specific heat capacity, C	740 J·Kg-1 K-1
Y (verify) (what is: Y/N?) Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Infobox references

Aluminium nitride (AlN) is a nitride of aluminium. Its wurtzite phase (w-AlN) is a wide band gap (6.2 eV) semiconductor material, giving it potential application for deep ultraviolet optoelectronics.

  History

AlN was first synthesized in 1877, but it was not until the middle of the 1980s that its potential for application in microelectronics was realized due to its relative high thermal conductivity for an electrical insulating ceramic (70–210 W·m⁻¹·K⁻¹ for polycrystalline material, and as high as 285 W·m⁻¹·K⁻¹ for single crystals).^[2]

  Stability and chemical properties

Aluminium nitride is stable at high temperatures in inert atmospheres and melts at 2800 °C. In a vacuum, AlN decomposes at ~1800 °C. In the air, surface oxidation occurs above 700°C, and even at room temperature, surface oxide layers of 5-10 nm have been detected. This oxide layer protects the material up to 1370°C. Above this temperature bulk oxidation occurs. Aluminium nitride is stable in hydrogen and carbon dioxide atmospheres up to 980°C.^[3]

The material dissolves slowly in mineral acids through grain boundary attack, and in strong alkalies through attack on the aluminium nitride grains. The material hydrolyzes slowly in water. Aluminium nitride is resistant to attack from most molten salts, including chlorides and cryolite.

  Manufacture

AlN is synthesized by the carbothermal reduction of aluminium oxide or by direct nitridation of aluminium. The use of sintering aids and hot pressing is required to produce a dense technical grade material.

  Applications

Metallization methods are available to allow AlN to be used in electronics applications similar to those of alumina and beryllium oxide.

Currently there is much research into developing light-emitting diodes to operate in the ultraviolet using the gallium nitride based semiconductors and, using the alloy aluminum gallium nitride, wavelengths as short as 250 nm have been achieved. In May 2006, an inefficient AlN LED emission at 210 nm has been reported.^[4]

Among the applications of AlN are

• opto-electronics,
• dielectric layers in optical storage media,
• electronic substrates, chip carriers where high thermal conductivity is essential,
• military applications,
• as a crucible to grow crystals of gallium arsenide,
• steel and semiconductor manufacturing.

Epitaxially grown thin film crystalline aluminium nitride is also used for surface acoustic wave sensors (SAW's) deposited on silicon wafers because of the AlN's piezoelectric properties. One application is an RF filter used in mobile phones called a thin film bulk acoustic resonator (FBAR). This is a MEMS device that uses aluminium nitride sandwiched between two metal layers.^[5]

  See also

• Boron nitride
• Aluminium phosphide
• Indium nitride

  References

  External links

• "AlN - Aluminium Nitride". Ioffe Database. Sankt-Peterburg: FTI im. A. F. Ioffe, RAN. http://www.ioffe.rssi.ru/SVA/NSM/Semicond/AlN/index.html. 
• "Electronic Structure of AlN". University Pennsylvania. http://www.lrsm.upenn.edu/~frenchrh/download/9308esaln.pdf. 
• "MSDS". University of Oxford. http://physchem.ox.ac.uk/MSDS/AL/aluminium_nitride.html. ^{[dead link]}
• AIN in Chinese AIN