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definition - Chemical_structure

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Chemical structure

                   

A chemical structure includes molecular geometry, electronic structure and crystal structure of molecules. Molecular geometry refers to the spatial arrangement of atoms in a molecule and the chemical bonds that hold the atoms together. Molecular geometry can range from the very simple, such as diatomic oxygen or nitrogen molecules, to the very complex, such as protein or DNA molecules. Molecular geometry can be roughly represented using a structural formula. Electronic structure describes the occupation of a molecule's molecular orbitals.

The theory of chemical structure was developed in the 1850s and 1860s by several chemists, including Friedrich August Kekule, Archibald Scott Couper, and Aleksandr Butlerov. These chemists demonstrated that the chemical compounds are not not composed of random clusters of atoms and functional groups, but have structures with a definite order formed according the valency of the composing atoms.

  Structure determination

Structural determination in chemistry is the process of determining the chemical structure of molecules. Practically, the end result of such process is the obtainment of the coordinates of the atoms in a molecule.[1] The methods by which one can determine the structure of a molecule include spectroscopy, such as nuclear magnetic resonance (NMR), infrared spectroscopy and Raman spectroscopy, electron microscopy, and x-ray crystallography (x-ray diffraction). The last technique can produce three-dimensional models at atomic-scale resolution, as long as crystals are available, as x-ray diffraction needs numerous copies of the molecule being studied that must also be arranged in an organised way.[1]

The following are common methods for determining the chemical structure (Structural elucidation) :

The following are common methods for determining the electronic structure:

  See also

  References

  1. ^ a b C406_lect07 (PDF, 936 KiB)
   
               

 

All translations of Chemical_structure


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