Fulvene
From Wikipedia
| Fulvene | |
|---|---|
Fulvene | |
other names 5-Methylene-1,3-cyclopentadiene | |
| Identifiers | |
| CAS number | 497-20-1 |
| PubChem | 136323 |
| SMILES | C=C1C=CC=C1 |
| Properties | |
| Molecular formula | C6H6 |
| Molar mass | 78.11 g/mol |
| Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) | |
| Infobox references | |
Fulvene is one of several hydrocarbons with the same formula as benzene, C6H6. Fulvenes include the derivatives of this simple hydrocarbon, which itself is rarely encountered.[1] Thiele is credited with discovering the scope of the reaction between cyclopentadiene and aldehydes and ketones that affords the brightly coloured fulvene derivatives.[2] Most fulvenes are prepared by the reactions starting from cyclopentadiene or sodium cyclopentadienyl.[3]
2,3,4,5-Tetramethylfulvene, abbreviated Me4Fv, is a relatively common ligand in organometallic chemistry. It typically results from the deprotonation of cationic pentamethylcyclopentadienyl complexes.[4]
References
- ↑ Bergmann, E. D. (1968). [Expression error: Missing operand for > "Fulvenes and Substituted Fulvenes"]. Chemical Reviews 68: 41–84. doi:.
- ↑ Thiele, J. (1900). [Expression error: Missing operand for > "Ueber Ketonreactionen bei dem Cyclopentadiën"]. Chemische Berichte 33: 666–673. doi:.
- ↑ Hafner, K.; Vöpel, K. H.; Ploss, G.; König, C. (1973). "6-(Dimethylamino)fulvene". Organic Syntheses Coll. Vol. 5: 431. http://www.orgsyn.org/orgsyn/pdfs/CV5P0431.pdf.
- ↑ Kreindlin, A. Z.; Rybinskaya, M. A. (2004). [Expression error: Missing operand for > "Cationic and Neutral Transition Metal Complexes with a Tetramethylfulvene or Trimethylallyldiene Ligand"]. Russian Chemical Reviews 73: 417–432. doi:.
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