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definition - Hydrogen_selenide

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Hydrogen selenide

                   
Hydrogen selenide
Identifiers
CAS number 7783-07-5 YesY
PubChem 533
ChemSpider 518 YesY
UN number 2202
KEGG C01528 YesY
ChEBI CHEBI:16503 YesY
RTECS number X1050000
Jmol-3D images Image 1
Properties
Molecular formula H2Se
Molar mass 80.98 g/mol
Appearance Colorless gas
Odor horseradish
Density 3.553 g/cm3
Melting point

-65.73 °C, 207 K, -86 °F

Boiling point

-41.25 °C, 232 K, -42 °F

Solubility in water 0.70 g/100 mL
Solubility soluble in CS2, phosgene
Acidity (pKa) 3.89
Structure
Molecular shape Bent
Hazards
MSDS ICSC 0284
EU Index 034-002-00-8
EU classification Highly Flammable (F+)
Toxic (T)
Dangerous for the environment (N)
R-phrases R23/25, R33, R50/53
S-phrases (S1/2), S20/21, S28, S45, S60, S61
NFPA 704
NFPA 704.svg
4
4
0
Flash point flammable gas
Related compounds
Other anions H2O
H2S
H2Te
H2Po
Other cations Na2Se
Ag2Se
Related compounds Arsine
 YesY (verify) (what is: YesY/N?)
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Infobox references

Hydrogen selenide is the inorganic compound with the formula H2Se. It is the simplest and virtually the only hydride of selenium. H2Se is a colorless, flammable gas under standard conditions. It is the most toxic selenium compound with an exposure limit: 0.05 ppm over an 8 hour period. This compound has a very irritating smell resembling that of decayed horseradish but smells of rotten eggs at higher concentrations.

Contents

  Structure and properties

H2Se adopts a "bent" structure with a H-Se-H bond angle of 91°. Consistent with this structure, three IR-active vibrational bands are observed: 2358, 2345, and 1034 cm−1.

The properties of H2S and H2Se are similar, although the selenide is more acidic with pKa = 3.89, and the second pKa = 11.0 at 25 °C. Reflecting its acidity, H2Se is soluble in water.

  Preparation

Industrially, it is produced by treating elemental selenium at T > 300 °C with hydrogen gas.[1] A number of routes to H2Se have been reported, which are suitable for both large and small scale preparations. In the laboratory, H2Se is usually prepared by the action of water on Al2Se3, concomitant with formation of hydrated alumina. A related reaction involves the acid hydrolysis of FeSe.[2]

Al2Se3 + 6 H2O 2 Al(OH)3 + 3 H2Se

H2Se can also be prepared by means of different methods based on the in situ generation in aqueous solution using boron hydride, Marsh test and Devarda's alloy. According to the Sonoda method, H2Se is generated from the reaction of H2O and CO on Se in the presence of Et3N.[3] H2Se can be purchased in cylinders.

  Reactions

Elemental selenium can be recovered from H2Se through a reaction with aqueous sulfur dioxide (SO2).

2 H2Se + SO2 2 H2O + Se + S

Its decomposition is used to prepare highly pure Se metal.

  Applications

H2Se is commonly used in the synthesis of Se-containing compounds. It adds across alkenes. Illustrative is the synthesis of selenoureas from nitriles.[4] Selenourea reaction H2Se gas is used to dope semiconductors with selenium.

  Safety

The gas is hazardous, being one of the most toxic compound of selenium and far more toxic than its congener hydrogen sulfide. The threshold limit value is 0.05 ppm. At high concentrations even exposure for less than a minute causes the gas to attack the eyes and mucous membranes causing cold-like symptoms for at least a few days afterwards. In Germany, the limit in drinking water is 0.008 mg/L, and the US EPA recommends a maximum contamination of 0.01 mg/L.[1][5]

  References

  1. ^ a b Bernd E. Langner "Selenium and Selenium Compounds" in Ullmann's Encyclopedia of Industrial Chemistry, 2005, Wiley-VCH, Weinheim. doi:10.1002/14356007.a23_525.
  2. ^ Féher, F. In "Handbook of Preparative Inorganic Chemistry"; Brauer, E., Ed.; Academic: New York, 1963; 1, p 418.
  3. ^ Sonoda, N.; Kondo K.; Nagano, K.; Kambe, N.; Morimoto, F. Angewandte Chemie, International Edition English 1980, vol. 19, page 308
  4. ^ V.I. Cohen "A Convenient Synthesis of Mono-, N,N′-Di-, and Trisubstituted Selenoureas from Methyl Carbamimidothioates (S-Methylpseudothioureas)" Synthesis, 1980, 60-3 (1980).
  5. ^ http://www.osha.gov/dts/chemicalsampling/data/CH_246700.html, OSHA GENERAL INDUSTRY PEL: 0.05 ppm, 0.2 mg/m3 ,OSHA CONSTRUCTION INDUSTRY PEL: 0.05 ppm, 0.2 mg/m3 TWA

  External links

   
               

 

All translations of Hydrogen_selenide


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